Journal of the American Chemical Society, 1994, Volume : 116, Numéro : 5
The 5-endo cyclization of the 2-formylbenzoyl radical (reaction 2) is shown to be a highly favored process relative to the alternative, 4-exo-trig ring...
Journal of the American Chemical Society, 1973, Volume : 95, Numéro : 19
The preparation of nortropane N-oxyl (8-azabicyclo[3.2. 1]octane N-oxyl) and some homologs and derivatives is described. This radical oxidizes hydrogen...
Journal of the American Chemical Society, 1973, Volume : 95, Numéro : 9
Di-tert-butyl ketoxime has been prepared by a new and simple procedure. It can be oxidized by a variety of oxidizing agents to a moderately stable free...
Journal of the American Chemical Society, 1973, Volume : 95, Numéro : 19
In isopentane at 25° a 0.1 M solution of nortropane N-oxyl (1) contains 0.0618 M of the free radical and a 0.1 M solution of 9-azabicyclo[3.3.1]nonane N-oxyl...
Journal of the American Chemical Society, 1973, Volume : 95, Numéro : 26
The differences in the heats of formation in solution of the stable free radicals, 2,2,6,6-tetramethylpiperid-4-one 1-oxyl (1a), 2,2,6,6-tetramethylpiperdine...